Preheat air fryer according to manufacturer's instructions to 350 degrees. Spray basket with non-stick spray.
Drizzle 1/2 tablespoon of oil over the pork.
Season the pork chops on both sides with the paprika, onion powder, garlic powder, and 1/2 teaspoon of salt.
Place pork chops in the air fryer basket and cook for 5 minutes.
While pork chops are cooking, add the broccoli, garlic, remaining 1/2 teaspoon of salt, and remaining oil to a bowl and toss to coat.
Open the air fryer and carefully flip the pork chops.
Add the broccoli to the basket and return to the air fryer.
Cook for 5 more minutes, stirring the broccoli halfway through.
Carefully remove the food from the air fryer and serve.
Notes
I used pork chops that were about 1/2 inch thick. If using thicker or thinner pork chops, adjust cook times accordingly.If doubling this recipe to feed a family of four, I recommend cooking all four pork chops at once (assuming your air fryer is large enough) and then transferring to a plate and covering tightly with foil while cooking the broccoli.